1-nitronaphthalene (purity)
α-Nitronaphthalene
CAS: 86-57-7;27254-36-0
Molecular Formula: C10H7NO2
1-nitronaphthalene (purity) - Names and Identifiers
| Name | α-Nitronaphthalene |
| Synonyms | UN2538 NCI-C01956 nci-c01956 1-Nitronaftalen 1-nitronaftalen Nitronaphthalene 1-nitronphthalene 1-NITRONAPHTHALENE α-Nitronaphthalene 1-nitro-naphthalen 1-nitronaphthalene Naphthalene, nitro- naphthalene,1-nitro- Mononitronaphthalene Naphthalene,1-nitro- alpha-nitronaphthalene ALPHA-NITRONAPHTHALENE naphthalene,alpha-nitro Naphthalene, mononitro- 1-nitronaphthalene (alpha) 1-nitronaphthalene (purity) Nitronaphthalene [UN2538] [Flammable solid] |
| CAS | 86-57-7 27254-36-0 |
| EINECS | 201-684-5 |
| InChI | InChI=1/C10H7NO2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H |
| InChIKey | RJKGJBPXVHTNJL-UHFFFAOYSA-N |
1-nitronaphthalene (purity) - Physico-chemical Properties
| Molecular Formula | C10H7NO2 |
| Molar Mass | 173.17 |
| Density | 1.223g/mLat 25°C(lit.) |
| Melting Point | 56 °C |
| Boling Point | 304°C(lit.) |
| Flash Point | 164 °C |
| Water Solubility | 0.022 g/L |
| Solubility | H2O: insoluble |
| Appearance | neat |
| Specific Gravity | 1.223 |
| Color | Light Yellow To Yellow |
| Merck | 14,6613 |
| BRN | 1867714 |
| Storage Condition | 2-8°C |
| Stability | Stable. Combustible. Incompatible with oxidizing agents, strong reducing agents. Mixtures with sulfuric or nitric acid are dangerous. |
| Refractive Index | 1.5200 (estimate) |
| Physical and Chemical Properties | Character yellow or colorless needle-like crystals. Melting Point: 56°C Boiling Point: 304°C(lit.) density: 1.223g/mL at 25°C(lit.) flash point: 164°C storage conditions: 2-8°c water solubility: 0.022g/L Merck: 14,6614 BRN: 1867714 CAS DataBase: 86-57-7(CAS DataBase Reference) NIST chemical Substance information: 86-57-7(NIST) EPA chemical Substance information: 86-57-7(EPA Substance) solubility insoluble in water. Soluble in ethanol, ether. |
| Use | Used in dye, pharmaceutical industry, also used as rubber antioxidant |
1-nitronaphthalene (purity) - Risk and Safety
| Risk Codes | R11 - Highly Flammable R25 - Toxic if swallowed R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R40 - Limited evidence of a carcinogenic effect R36/37/38 - Irritating to eyes, respiratory system and skin. R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S16 - Keep away from sources of ignition. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S28A - S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | UN 2538 4.1/PG 3 |
| WGK Germany | 2 |
| RTECS | QJ9720000 |
| HS Code | 29042000 |
| Hazard Note | Flammable/Toxic |
| Hazard Class | 4.1 |
| Packing Group | III |
1-nitronaphthalene (purity) - Reference Information
| (IARC) carcinogen classification | 3 (Vol. 46) 1989 |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| purpose | for the preparation of dyes, pesticides and rubber antioxidant, etc. The product is for dyes, pesticides, rubber additives and other intermediates in organic synthesis. used in dye, pharmaceutical industry, also used as rubber antioxidant |
| production method | is obtained from the nitration of naphthalene. In practical industrial production, a portion of the mixed acid required for the reaction can be reused. 600kg of the spent acid obtained from the above batch nitration was added to a glass-lined reaction pan, and under cooling, 98% of 100% sulfuric acid and of nitric acid were further added thereto, followed by stirring to prepare a mixed acid for use. 800kg of the last nitrated waste acid was added to the reaction pot, and 1550kg of refined naphthalene and the mixed acid prepared above were added. The refined naphthalene and the mixed acid were added three times, and the temperature was controlled at 50-55 °c. After addition, the temperature was raised to 65 ℃ for 3H. When the freezing point is ≥ 51 ℃, nitrifying waste acid is separated. The reaction was washed to neutrality with hot water to give 1-nitronaphthalene. |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-10 22:29:15
